The MPI-Mainz UV/VIS Spectral Atlas

of Gaseous Molecules of Atmospheric Interest

www.uv-vis-spectral-atlas-mainz.org

Hannelore Keller-Rudek1, Geert K. Moortgat2, Rolf Sander2, Rüdiger Sörensen1

1Satellite Group

2Atmospheric Chemistry Division

Max-Planck Institute for Chemistry
Mainz, Germany


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When referring to the Spectral Atlas, please cite our publication:

Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen, R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013), DOI: 10.5194/essd-5-365-2013


Cross Sections / Organics (N-compounds) / Peroxynitrates / CF3OC(O)OONO2 / Malanca(2009)_273K_200-330nm

DATAFILE: CF3OC(O)OONO2_Malanca(2009)_273K_200-330nm.txt
NAME: trifluoromethoxycarbonyl peroxy nitrate
FORMULA: CF3OC(O)OONO2
AUTHOR(YEAR): Malanca(2009)
T: 273K
λ: 200-330nm
BIBLIOGRAPHY: F.E. Malanca, M.D. Manetti, M.S. Chiappero, P. Gallay, and G.A. Argüello, "Photochemistry and absorption cross-sections temperature dependence of trifluoromethoxycarbonyl peroxy nitrate (CF3OC(O)OONO2)", J. Photochem. Photobiol. A: Chem. 205, 44-50 (2009); DOI: 10.1016/j.jphotochem.2009.04.003
COMMENTS: Averages over 5-nm intervals of the spectrum recorded at a resolution of 1 nm using a diode array spectrometer.

The representation of log σ vs. T leads to linear fits according to

log10 σ(T) = B × T + log10 σ(0 K).

The intercepts σ(0 K) and slopes B at selected wavelengths are as follows (one standard deviations in brackets):

-----------------------------------------------------
λ  103 B   1020 σ(0 K)
(nm) (K-1)    (cm2 molecule-1)
-----------------------------------------------------
290 1.9 (0.2)   0.151 (0.008)
295 2.0 (0.2)   0.085 (0.004)
300 2.5 (0.2)   0.035 (0.002)
305 3.43 (0.06)  0.0115 (0.0002)
310 7.2 (0.3)   5.3 (0.4)×10-4
315 9.2 (2)    -
320 20(5)    -

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